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Organic redox-active molecules for alkaline aqueous redox flow batteries

Alkaline aqueous organic redox flow batteries of high energy and power densities using mixed naphthoquinone derivatives. Chem Eng J (2020) C. Mirle et al. Crossover-free hydroxy-substituted quinone anolyte and potassium ferrocyanide catholyte for aqueous alkaline organic redox flow battery. Catal Today (2021) M. Qin et al. Redox-active anthraquinone

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A Neutral pH Aqueous Organic–Organometallic Redox Flow Battery

We demonstrate an aqueous organic and organometallic redox flow battery utilizing reactants composed of only earth-abundant elements and operating at neutral pH. The positive electrolyte contains bis((3-trimethylammonio)propyl)ferrocene dichloride, and the negative electrolyte contains bis(3-trimethylammonio)propyl viologen tetrachloride; these are separated

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A Sustainable Redox Flow Battery with Alizarin-Based Aqueous Organic

To achieve sustainable development, biomass materials are alternative options for mitigating the problems associated with energy and the environment. Recently, soluble anthraquinones in aqueous redox flow batteries have attracted extensive attention. Inspired by a natural anthraquinone dye named alizarin, here we report an affordable, sustainable, and

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Alkaline naphthoquinone‐based redox flow batteries with a

In this study, the performance of alkaline aqueous organic redox flow battery (AORFB) using an isomeric mixture of 1,2-naphthoquinone-4-sulfonic acid sodium salt and 2

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Perspectives on aqueous organic redox flow batteries

Aqueous organic redox flow batteries (AORFBs) have pioneered new routes for large-scale energy storage. The tunable nature of redox-active organic molecules provides a

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Two-electron storage electrolytes for aqueous organic

Aqueous organic redox flow batteries (AORFBs) are promising candidates for the large-scale storage of intermittent renewable energy because of their technological advantages of decoupled power and capacity,

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Alkaline naphthoquinone‐based redox flow batteries with a

In this study, the performance of alkaline aqueous organic redox flow battery (AORFB) using an isomeric mixture of 1,2-naphthoquinone-4-sulfonic acid sodium salt and 2-hydroxy-1,4-naphthoquinone (NQSO) and potassium ferrocyanide (FeCN) as active materials dissolved in potassium hydroxide (KOH) is enhanced with replacing commercial Nafion

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Alkaline quinone flow battery | Science

We report an alkaline flow battery based on redox-active organic molecules that are composed entirely of Earth-abundant elements and are nontoxic, nonflammable, and safe for use in residential and commercial

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Perspectives on aqueous organic redox flow batteries

Aqueous organic redox flow batteries (AORFBs) have pioneered new routes for large-scale energy storage. The tunable nature of redox-active organic molecules provides a robust foundation for creating innovative AORFBs with exceptional performance.

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Alkaline aqueous organic redox flow batteries of high energy

Mixture of 1,2-naphthoquinone-4-sulfonic acid sodium salt (NQ-S) and 2-hydroxy-1,4-naphthoquinone (Lawsone) is used as negative active species for aqueous organic redox flow battery (AORFB), while ferrocyanide (FeCN) is considered as positive active species in alkaline electrolyte. NQ-S is initially transformed to NQ-OH that has the same chemical

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Molecular Engineering of an Alkaline Naphthoquinone Flow Battery

Aqueous organic redox flow batteries (AORFBs) have recently gained significant attention as a potential candidate for grid-scale electrical energy storage. Successful implementation of this technology will require redox-active organic molecules with many desired properties. Here we introduce a naphthoquinone dimer, bislawsone, as the redox

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High-Performance Alkaline Organic Redox Flow Batteries Based

Aqueous redox flow batteries (ARFBs) based on the electrolyte solutions of redox-active organic molecules are very attractive for the application of large-scale electrochemical energy storage. We propose a high-performance ARFB system utilizing 2-hydroxy-3-carboxy-1,4-naphthoquinone (2,3-HCNQ) and K 4 Fe(CN) 6 as the anolyte and catholyte

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Pd2+-coordinated polybenzimidazole membranes with fast and

A comprehensive comparison of EE between QPBI-10PBI-Pd and other ion exchange membranes utilized in alkaline aqueous organic redox flow batteries reported in recent years has been conducted (Fig. 6 d and Table S1). The exemplary performances suggest that QPBI-xPBI-Pd membrane with high conductivity and outstanding stability is promising for deployment in

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Membraneless Micro Redox Flow Battery: From

Membraneless Alkaline Quinone Micro Redox Flow Battery (MAQMRFB): Anthraquinone and Ferrocyanide . Vanadium electrolyte is commonly employed in commercial redox flow batteries due to its unique

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A redox-flow battery with an alloxazine-based

Redox-flow batteries (RFBs) can store large amounts of electrical energy from variable sources, such as solar and wind. Recently, redox-active organic molecules in aqueous RFBs have drawn

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Alkaline aqueous organic redox flow batteries of high energy

Mixture of 1,2-naphthoquinone-4-sulfonic acid sodium salt (NQ-S) and 2-hydroxy-1,4-naphthoquinone (Lawsone) is used as negative active species for aqueous organic redox flow battery (AORFB), while ferrocyanide (FeCN) is considered as positive active species in alkaline electrolyte.

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High-Performance Alkaline Organic Redox Flow

Aqueous redox flow batteries (ARFBs) based on the electrolyte solutions of redox-active organic molecules are very attractive for the application of large-scale electrochemical energy storage. We propose a high-performance ARFB

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Aqueous Organic Redox Flow Battery

Aqueous organic redox flow batteries (AORFBs) have recently gained significant attention as a potential candidate for grid-scale electrical energy storage. Successful implementation of this technology will require redox-active organic

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Organic redox-active molecules for alkaline aqueous redox flow batteries

The aqueous alkaline organic hybrid flow batteries using SMRT reaction have great development potential in large-scale energy storage systems. The strategic focus on harnessing the potential of these solid materials via SMRT to enhance the energy density of flow batteries represents a promising direction for future research initiatives.

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Alkaline naphthoquinone‐based redox flow batteries with a

In this study, the performance of alkaline aqueous organic redox flow battery (AORFB) using an isomeric mixture of 1,2-naphthoquinone-4-sulfonic acid sodium salt and 2-hydroxy-1,4-naphthoquinone (NQSO) and potassium ferrocyanide (FeCN) as active materials dissolved in potassium hydroxide (KOH) is enhanced with replacing commercial

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Alkaline quinone flow battery | Science

We report an alkaline flow battery based on redox-active organic molecules that are composed entirely of Earth-abundant elements and are nontoxic, nonflammable, and safe for use in residential and commercial environments. The battery operates efficiently with high power density near room temperature. These results demonstrate the

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Comprehensive study of the performance of alkaline

Alkaline‐based organic redox flow batteries (AORFBs) attract significant interest because they can retain the advantages of vanadium redox flow batteries (VRFBs) while being low‐cost because expensive vanadium is

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Alkaline aqueous organic redox flow batteries of high energy and

Mixture of 1,2-naphthoquinone-4-sulfonic acid sodium salt (NQ-S) and 2-hydroxy-1,4-naphthoquinone (Lawsone) is used as negative active species for aqueous

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Comprehensive study of the performance of alkaline organic redox flow

Alkaline‐based organic redox flow batteries (AORFBs) attract significant interest because they can retain the advantages of vanadium redox flow batteries (VRFBs) while being low‐cost because expensive vanadium is replaced with easily synthesizable metal‐free organic compounds and earth‐abundant raw materials. A comprehensive

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Aqueous Organic Redox Flow Battery

EE: 62.6% pH values of the electrolytes were adjusted to 7.0 using a diluted NH3 ꞏH2O or HCl solution. II. Alkaline AORFBs. Thanks for your attention!

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Recent developments in organic redox flow batteries: A critical

To obtain these desirable properties for all-organic flow batteries, tremendous improvements need to be made in existing systems, (>0.5 V vs. SHE in alkaline media) at reasonable solubility (>0.6 mol dm −3) [75]. Recent research and development in the redox flow battery community has focused on the identification, synthesis and modification of novel redox

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Development of organic redox‐active materials in aqueous flow batteries

Furthermore, zinc–organic hybrid flow batteries could be engineered with high voltage. For example, Park et al. Moreover, pH-neutral or weak alkaline electrolyte (pH 7−10) should be most promising for future AORFBs, especially if the solubility of organic redox species is further improved in this pH region, because the corrosion and undesired side reactions including

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Two-electron storage electrolytes for aqueous organic redox flow batteries

Aqueous organic redox flow batteries (AORFBs) are promising candidates for the large-scale storage of intermittent renewable energy because of their technological advantages of decoupled power and capacity, convenient scale up, diverse organic molecules, potential low cost, and high safety.

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6 FAQs about [Alkaline organic flow battery]

Can redox-active organic molecules be used in alkaline flow batteries?

The battery operates efficiently with high power density near room temperature. These results demonstrate the stability and performance of redox-active organic molecules in alkaline flow batteries, potentially enabling cost-effective stationary storage of renewable energy.

Are alkaline flow batteries safe?

We report an alkaline flow battery based on redox-active organic molecules that are composed entirely of Earth-abundant elements and are nontoxic, nonflammable, and safe for use in residential and commercial environments. The battery operates efficiently with high power density near room temperature.

What is alkaline benzoquinone aqueous flow battery?

Alkaline benzoquinone aqueous flow battery for large-scale storage of electrical energy Renewable-lawsone-based sustainable and high-voltage aqueous flow battery Organic redox species in aqueous flow batteries: redox potentials, chemical stability and solubility

Are aqueous organic redox flow batteries suitable for grid-scale electrical energy storage?

Aqueous organic redox flow batteries (AORFBs) have recently gained significant attention as a potential candidate for grid-scale electrical energy storage. Successful implementation of this technology will require redox-active organic molecules with many desired properties.

Are aqueous organic redox flow batteries safe?

In contrast, aqueous organic redox flow batteries (AORFBs) can be safely operated, and the operation in high current density is possible.

Are organic redox flow batteries better than metal based RFBS?

Such organic redox flow batteries (ORFBs) have more benefits than the metal-based RFBs , , . First, the cost of both active species is generally cheaper. Second, the possible operational temperature window for ORFBs is wider than that of VRFBs, leading to fast redox reactivity in a high temperature range.

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