Kang IS, Lee YS, Kim DW (2013) Improved cycling stability of lithium electrodes in rechargeable lithium batteries. J Electrochem Soc 161:A53–A57. Article Google Scholar Miao LX, Wang
Customer ServiceSilicon (Si) is recognized as a promising candidate for next-generation lithium-ion batteries (LIBs) owing to its high theoretical specific capacity (~4200 mAh g −1), low working potential (<0.4 V vs. Li/Li +), and abundant reserves.
Customer ServiceReal-time monitoring of NE potential is highly desirable for improving battery performance and safety, as it can prevent lithium plating which occurs when the NE potential drops below a threshold value. This paper proposes an easy-to-implement framework for real-time estimation of the NE potential of LIBs.
Customer ServiceSolid-state lithium metal batteries show substantial promise for overcoming theoretical limitations of Li-ion batteries to enable gravimetric and volumetric energy densities
Customer ServiceBy reducing volume changes and polarization phenomena, nanosilicon materials with high specific surface areas and lithium storage capacities can increase the cycle life and energy density of
Customer ServiceSilicon (Si) is recognized as a promising candidate for next-generation lithium-ion batteries (LIBs) owing to its high theoretical specific capacity (~4200 mAh g −1), low working potential (<0.4 V vs. Li/Li +), and
Customer ServiceLithium (Li) metal is widely recognized as a highly promising negative electrode material for next-generation high-energy-density rechargeable batteries due to its exceptional specific capacity (3860 mAh g −1), low
Customer ServiceSolid-state lithium metal batteries show substantial promise for overcoming theoretical limitations of Li-ion batteries to enable gravimetric and volumetric energy densities upwards of 500 Wh kg
Customer ServiceNiCo 2 O 4 has been successfully used as the negative electrode of a 3 V lithium-ion battery. It should be noted that the potential applicability of this anode material in commercial lithium-ion batteries requires a careful selection of the cathode material with sufficiently high voltage, e.g. by using 5 V cathodes LiNi 0.5 Mn 1.5 O 4 as
Customer ServiceLithium (Li) metal is widely recognized as a highly promising negative electrode material for next-generation high-energy-density rechargeable batteries due to its exceptional specific capacity (3860 mAh g −1), low electrochemical potential (−3.04 V vs. standard hydrogen electrode), and low density (0.534 g cm −3).
Customer ServiceReal-time monitoring of NE potential is highly desirable for improving battery performance and safety, as it can prevent lithium plating which occurs when the NE potential
Customer ServiceCyclic carbonate-based electrolytes are widely used in lithium-ion batteries, such as ethylene carbonate (EC), and they go through reduction or oxidation reactions on the surface of negative or positive electrodes, to form the well-known electrode-electrolyte interface film (EEI).
Customer ServiceThis review considers electron and ion transport processes for active materials as well as positive and negative composite electrodes. Length and time scales over many orders of magnitude are relevant ranging from
Customer ServiceCyclic carbonate-based electrolytes are widely used in lithium-ion batteries, such as ethylene carbonate (EC), and they go through reduction or oxidation reactions on the surface of negative or positive electrodes, to form
Customer ServiceBy reducing volume changes and polarization phenomena, nanosilicon materials with high specific surface areas and lithium storage capacities can increase the cycle life and energy density of
Customer ServiceKang IS, Lee YS, Kim DW (2013) Improved cycling stability of lithium electrodes in rechargeable lithium batteries. J Electrochem Soc 161:A53–A57. Article Google Scholar Miao LX, Wang WK, Wang AB, Yuan KG, Yang YS (2013) A high sulfur content composite with core–shell structure as cathode material for Li-S batteries. J Mater Chem A 1:11659
Customer ServiceThis paper illustrates the performance assessment and design of Li-ion batteries mostly used in portable devices. This work is mainly focused on the selection of negative electrode materials, type of electrolyte, and selection of positive electrode material. The main software used in COMSOL Multiphysics and the software contains a physics
Customer ServiceNiCo 2 O 4 has been successfully used as the negative electrode of a 3 V lithium-ion battery. It should be noted that the potential applicability of this anode material in commercial lithium-ion batteries requires a careful selection of the cathode material with
Customer ServiceThis review considers electron and ion transport processes for active materials as well as positive and negative composite electrodes. Length and time scales over many orders of magnitude are relevant ranging from atomic arrangements of materials and short times for electron conduction to large format batteries and many years of operation
Customer ServiceThis paper illustrates the performance assessment and design of Li-ion batteries mostly used in portable devices. This work is mainly focused on the selection of negative
Customer ServiceLithium (Li) metal is widely recognized as a highly promising negative electrode material for next-generation high-energy-density rechargeable batteries due to its exceptional specific capacity (3860 mAh g −1), low electrochemical potential (−3.04 V vs. standard hydrogen electrode), and low density (0.534 g cm −3).
The main problem is the high voltage (1.8 V) of the plateau, particularly as compared with carbon materials. Again this can be solved by combination with a sufficiently high potential positive electrode in a lithium-ion battery.
More recently, a new perspective has been envisaged, by demonstrating that some binary oxides, such as CoO, NiO and Co 3 O 4 are interesting candidates for the negative electrode of lithium-ion batteries when fully reduced by discharge to ca. 0 V versus Li , .
During the initial lithiation of the negative electrode, as Li ions are incorporated into the active material, the potential of the negative electrode decreases below 1 V (vs. Li/Li +) toward the reference electrode (Li metal), approaching 0 V in the later stages of the process.
Two lines of research can be distinguished: (i) improvement of LiCoO 2 and carbon-based materials, and (ii) replacement of the electrode materials by others with different composition and structure. Concerning the positive electrode, the replacement of lithium cobaltate has been shown to be a difficult task.
The limitations in potential for the electroactive material of the negative electrode are less important than in the past thanks to the advent of 5 V electrode materials for the cathode in lithium-cell batteries. However, to maintain cell voltage, a deep study of new electrolyte–solvent combinations is required.
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