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Zirconium-Doped Zinc Oxide Nanoparticles as Cathode Interfacial Layers

Low-temperature zinc oxide nanoparticles (ZnO NPs) are widely applied as cathode interfacial layers (CILs) for rigid and flexible organic solar cells. However, the inferior optoelectronic properties of ZnO NPs constrain the improvement in the photovoltaic performance and enhance the thickness sensitivity. Herein, upon application of

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Zirconium-doped indium oxide electrodes for

A research team including scientists from Italian module manufacturer 3Sun has tested new zirconium-doped indium oxide electrodes in commercial heterojunction solar modules. The new electrodes

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Manipulation of Zinc Oxide with Zirconium Doping for Efficient

By using ZnO:Zr as ETL in inverted device configuration, the maximum power conversion efficiency (PCE) of PM6:Y6:PC 71 BM solar cell devices is up to 17.2%, which makes an enhancement of 9.55% compared to ZnO-based devices (15.7%). As the thickness of ZnO:Zr ETL increases to ≈60 nm, the presence of the lower parasitic absorption together with uniform

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Solar Energy Materials and Solar Cells

To test the performances of a proof-of-concept solar cell based on IZrO

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Zirconium-doped indium oxide electrodes for heterojunction solar cells

A European research group led by Italy''s University of Catania has tested the use of zirconium (Zr)-doped indium oxide (In2O3) as a transparent conductive film in the silicon heterojunction (HJT)...

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Zirconium-Doped Zinc Oxide Nanoparticles as Cathode Interfacial Layers

Low-temperature zinc oxide nanoparticles (ZnO NPs) are widely applied as cathode interfacial layers (CILs) for rigid and flexible organic solar cells. However, the inferior optoelectronic properties of ZnO NPs constrain the improvement in the photovoltaic performance and enhance the thickness sensitivity. Herein, upon application of this ZnO:Zr NP as a CIL for

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Zr-doped indium oxide films for silicon heterojunction solar cells

IZrO film was used as a transparent conducting electrode in silicon

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Zirconium Doping to Enable High-Efficiency and Stable CsPbI2Br

All-inorganic wide-bandgap perovskite CsPbI2Br has attracted much attention because of its inherent thermal stability and ideal bandgap for the front subcell of tandem solar cells (TSCs). However, the low power conversion efficiency (PCE) and poor moisture stability of CsPbI2Br still restrict its future commercialization. Herein, zirconium tetrachloride (ZrCl4) was

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Double‐Layered Zirconia Films for Carbon‐Based Mesoscopic

Carbon-based mesoscopic perovskite solar cells (PSCs) and photodetectors were fabricated with the application of double-layered ZrO 2 films, consisting of zirconia nanoparticles and microparticles for the first and the second layer, respectively. This assembly exploits the ability of the zirconia microparticles to scatter and hence diffuse the incident light,

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Zirconium Doping to Enable High-Efficiency and Stable CsPbI

All-inorganic wide-bandgap perovskite CsPbI 2 Br has attracted much attention because of its inherent thermal stability and ideal bandgap for the front subcell of tandem solar cells (TSCs). However, the low power conversion efficiency (PCE) and poor moisture stability of CsPbI 2 Br still restrict its future commercialization.

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High performance polymer solar cells with as-prepared zirconium

Here we demonstrate high performance PSCs by employing as-prepared

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Zirconium-Doped Zinc Oxide Nanoparticles as Cathode

Low-temperature zinc oxide nanoparticles (ZnO NPs) are widely applied as cathode interfacial layers (CILs) for rigid and flexible organic solar cells. However, the inferior optoelectronic properties of ZnO NPs

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Zirconium oxide films: deposition techniques and their

In the present review, various deposition techniques used to grow zirconium oxide thin films and their application to enhance the quantum efficiency of titanium oxide (TiO2) based dye-sensitized solar cells (DSSCs) are discussed. Also, the modulated performances of DSSCs fabricated by growing the conformal ZrO2 insulating films to

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Efficient silicon solar cells with highly conductive

Efficient carrier transport and suppressed interface recombination at back contact are essential for high-efficiency solar cells. Herein, we developed a zirconium nitride (ZrN) film with a low film resistivity of 1.6 ×

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High-Performance Inverted Polymer Solar Cells with

Inverted polymer solar cells incorporating solution-processed zirconium acetylacetonate (ZrAcac) buffer layers were demonstrated. The optimal device delivered a power conversion efficiency up to 9.2%, displaying ∼20%

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Solution-processed and annealing-free zirconium acetylacetonate

Recently, zirconium acetylacetonate (ZrAcac), as a stable electron-selective material, has been considered as a simple and effective alternative to traditional interlayers and has been integrated in perovskite and polymer solar cells successfully (Chen et al., 2017, Fan and Zhu, 2016, Hancox et al., 2015, Lu et al., 2020).The ZrAcac was first served as an effective

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Zirconium Doping to Enable High-Efficiency and Stable

All-inorganic wide-bandgap perovskite CsPbI 2 Br has attracted much attention because of its inherent thermal stability and ideal bandgap for the front subcell of tandem solar cells (TSCs). However, the low power conversion

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Effective interface treatment by zirconium acetylacetonate for

Here, we demonstrate that zirconium acetylacetonate (ZrAcac) provides both effective methylammonium-rich perovskites surface passivation and excellent interfacial charge transport channel between the perovskite and fullerene-based

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High-Performance Inverted Polymer Solar Cells with Zirconium

Inverted polymer solar cells incorporating solution-processed zirconium acetylacetonate (ZrAcac) buffer layers were demonstrated. The optimal device delivered a power conversion efficiency up to 9.2%, displaying ∼20% improvement compared with the device of conventional configuration. The performance improvement by adopting ZrAcac as the cathode buffer layer is attributed to

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Solar Energy Materials and Solar Cells

To test the performances of a proof-of-concept solar cell based on IZrO electrodes, we deposited IZrO films on bi-facial Silicon Heterojunction solar cells, extracted from the production line right before the deposition of the transparent electrode layers. The incomplete cell was fabricated by the 3SUN company with the structure of a

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Efficient silicon solar cells with highly conductive zirconium

Efficient carrier transport and suppressed interface recombination at back contact are essential for high-efficiency solar cells. Herein, we developed a zirconium nitride (ZrN) film with a low film resistivity of 1.6 × 10 −4 Ω cm as an

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Zr-doped indium oxide films for silicon heterojunction solar cells

IZrO film was used as a transparent conducting electrode in silicon heterojunction (SHJ) solar cells. The SHJ cell (274.15 cm 2) has a conversion efficiency of 24.55%, open-circuit voltage of 747.47 mV, short circuit current density of 39.98 mA/cm 2, and filling factor of 82.18%.

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High performance polymer solar cells with as-prepared zirconium

Here we demonstrate high performance PSCs by employing as-prepared zirconium acetylacetonate (a-ZrAcac) film spin-cast from its ethanol solution as cathode buffer layer.

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High‐Efficiency Nonfullerene Organic Solar Cells Enabled by

Organic solar cells (OSCs) are promising photovoltaic devices and zinc oxide (ZnO) is a commonly used electron transport layer (ETL) in OSCs. However, the conventional spin-coating ZnO layer is currently limiting its efficiency potential. Herein, it is shown for the first time that atomic layer deposition (ALD), which allows for controlled thin film growth with atomic

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Optimization of a SnO2-Based Electron Transport Layer Using Zirconium

The development of high-quality SnO 2 ETLs with a large coverage and that are pinhole-free is crucial to enhancing the performance and stability of the perovskite solar cells (PSCs). In this work, zirconium acetylacetonate (ZrAcac) was introduced to form a double-layered ETL, in which an ideal cascade energy level alignment is obtained.

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High-Performance Inverted Polymer Solar Cells with Zirconium

Inverted polymer solar cells incorporating solution-processed zirconium acetylacetonate (ZrAcac) buffer layers were demonstrated. The optimal device delivered a power conversion efficiency up to 9.2%, displaying ∼20% improvement compared with the device of conventional configuration.

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6 FAQs about [Zirconium Solar Cells]

Can zirconium oxide films be used in dye-sensitized solar cells?

The review enlightens the contributions on the synthesis of zirconium oxide films and their applications in dye-sensitized solar cells which will help the vision scientists, researchers, and trainees to intensify their research work on ZrO 2. Deposition techniques of thin films can be categorized into chemical and physical methods.

Can Zirconium acetylacetonate be used in inverted solar cells?

Effective interface treatments by inserting zirconium acetylacetonate between the perovskite and fullerene-based electron transport layer led to high-performance and stable inverted solar cells. 1. Introduction

Does zirconium content affect photovoltaic properties of DSSC?

It has been shown that x = 5% of zirconium content, an increased V OC has been achieved [129, 131]. They have studied the influence of electrical properties of Ti 1 − x Zr x O 2 on the photovoltaic properties of the DSSC. By increasing zirconium content, a monotone increase in lattice constant and hence increase in V OC were observed.

What causes photoluminescence in zirconium?

The study proposed that the photoluminescence mechanism was originated from the emission of a recombination center related to oxygen vacancies formed during anodization of zirconium. Simka et al. reported anodic oxidation of zirconium. A solution containing KOH and K 2 SiO 3 was used for oxidation process.

Can meosoporous zirconia-based dye-sensitized solar cells improve conversion efficiency?

Meosoporous zirconia-based dye-sensitized solar cells can change the overall scenario if conversion efficiency is enhanced. Photovoltaic devices are economical and clean sources of energy, and hence, they are studied on large scale.

Can zirconia film be used as a photoanode?

The deposition techniques reported by various research groups discussed here are very much practical. The use of ZrO 2 film as a photoanode is not yet reported, but mesoporous zirconia films are being used in different manners in enhancing the quantum efficiency of TiO 2 -based dye-sensitized solar cells.

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