Anode-free zinc new energy battery

Now, scientists have developed a proof-of-concept, rechargeable zinc-ion battery that forgoes a thick anode, giving it a relatively high energy density ( Nano Lett. 2021, DOI: 10.1021/acs.nanolett.
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Stable Aqueous Anode‐Free Zinc Batteries Enabled by Interfacial

Anode-free zinc batteries (AFZBs) are proposed as promising energy storage systems due to their high energy density, inherent safety, low cost, and simplified fabrication process. However, rapid capacity fading caused by the side reactions between the in situ formed zinc metal anode and electrolyte hinders their practical applications. To

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An artificial β-PVDF nanofiber layer for dendrite-free zinc anode

Owing to the merits of environmental friendliness and sustainability, aqueous zinc ion battery (AZIB) is considered as a promising energy storage system. Nevertheless, the further application of AZIB is largely limited by the growth of zinc dendrite and hydrogen evolution reaction of Zn anode. Here, a β-polyvinylidene fluoride (β-PVDF) nanofiber modified by 1-butyl

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An Anode-Free Zn–MnO2 Battery | Nano Letters

Using this anode-free configuration, we showcase a Zn–MnO 2 battery prototype, showing 68.2% capacity retention after 80 cycles. Our anode-free design opens a new direction for implementing aqueous Zn-based

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An anode-free zinc-ion battery | C&EN Global Enterprise

Now, scientists have developed a proof-of-concept, rechargeable zinc-ion battery that forgoes a thick anode, giving it a relatively high energy density ( Nano Lett. 2021, DOI: 10.1021/acs.nanolett.0c04519 ). Husam N. Alshareef and Yunpei Zhu of King Abdullah University of Science and Technology and Yi Cui of Stanford University preloaded the

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Co-Solvent Electrolyte Engineering for Stable Anode-Free Zinc

Anode-free metal batteries can in principle offer higher energy density, but this requires them to have extraordinary Coulombic efficiency (>99.7%). Although Zn-based metal batteries are promising for stationary storage, the parasitic side reactions make anode-free batteries difficult to achieve in practice. In this work, a salting-in-effect-induced hybrid electrolyte is proposed as an

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An anode-free zinc-ion battery | C&EN Global Enterprise

For rechargeable batteries, zinc chemistry presents a low-cost and potentially safer option than lithium and sodium. Those two metals typically use flammable organic electrolytes, while zinc is stable in air and compatible with water-based electrolytes. Now, scientists have developed a proof-of-concept, rechargeable zinc-ion battery that forgoes a thick anode, giving it a relatively

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An anode-free zinc-ion battery | C&EN Global

Now, scientists have developed a proof-of-concept, rechargeable zinc-ion battery that forgoes a thick anode, giving it a relatively high energy density ( Nano Lett. 2021, DOI: 10.1021/acs.nanolett.0c04519 ). Husam N. Alshareef and Yunpei

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Zinc battery goes to anode-free

The zinc (Zn) batteries have challenges include uncontrollable dendritic growth, unreasonable negative to positive ratio and limited areal capacity. This highlight presents the latest

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Recent advances in zinc anodes for high-performance aqueous

For the construction of aqueous energy storage devices, metallic zinc has so far remained the most ideal anode candidate due to its high electrical conductivity, easy processability, high compatibility/stability in water, non-flammability, low toxicity, comparatively low price (ca. 2 USD kg −1), and high abundance [20, 21].More importantly, Zn anode possesses

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Stable anode-free zinc-ion batteries enabled by alloy network

Newly-proposed anode-free zinc-ion batteries (ZIBs) are promising to remarkably enhance the energy density of ZIBs, but are restricted by the unfavorable zinc deposition interface that causes poor cycling stability. Herein, we report a Cu-Zn alloy network-modulated zinc deposition interface to achieve stable anode-free ZIBs. The

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Constructing robust heterostructured interface for anode-free zinc

An anode-free Zn-Br2 battery using the Sb/Sb2Zn3-heterostructured interface@Cu anode shows an attractive energy density of 274 Wh kg−1 with a practical

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Constructing robust heterostructured interface for anode-free zinc

An anode-free Zn-Br2 battery using the Sb/Sb2Zn3-heterostructured interface@Cu anode shows an attractive energy density of 274 Wh kg−1 with a practical pouch cell energy density of 62 Wh...

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Identifying iodide-ion regulation of early-stage zinc

Anode-free aqueous zinc (Zn) metal batteries (AZMBs) have the advantage of providing higher energy density. However, without excess Zn metal, their cycling life is highly dependent on the reversibility of Zn

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An Anode-Free Zn–Graphite Battery

Thanks to efficient Zn plating–stripping and TFSI − intercalation–deintercalation, an anode-free Zn–graphite dual-ion battery that exhibits impressive cycling stability with 82% capacity retention after 1000

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An Anode-Free Zn–Graphite Battery

Thanks to efficient Zn plating–stripping and TFSI − intercalation–deintercalation, an anode-free Zn–graphite dual-ion battery that exhibits impressive cycling stability with 82% capacity retention after 1000 cycles is constructed.

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An Anode-Free Zn–MnO2 Battery | Nano Letters

Using this anode-free configuration, we showcase a Zn–MnO 2 battery prototype, showing 68.2% capacity retention after 80 cycles. Our anode-free design opens a new direction for implementing aqueous Zn-based batteries in energy storage systems. To access this article, please review the available access options below. Read this article for 48 hours.

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Zinc battery goes to anode-free

The zinc (Zn) batteries have challenges include uncontrollable dendritic growth, unreasonable negative to positive ratio and limited areal capacity. This highlight presents the latest development to resolve the uncontrollable Zn dendrite formation at high areal capacities of 200 mAh·cm –2 through a two-dimensional metal/metal-Zn alloy

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Materials design for high-energy-density anode-free batteries

Anode-free batteries (AFBs) with no excess metal anode are considered as promising alternatives for next-generation energy storage technologies that possess the merits of high safety, high energy density, low cost, and simple manufacturing. 5 AFBs consist of cathodic current collectors, cathode materials, separators, electrolytes, and anodic current collectors.

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Stable anode-free zinc-ion batteries enabled by alloy network

Newly-proposed anode-free zinc-ion batteries (ZIBs) are promising to remarkably enhance the energy density of ZIBs, but are restricted by the unfavorable zinc deposition interface that causes poor cycling stability. Herein, we report a Cu-Zn alloy network-modulated zinc deposition interface to achieve stable anode-free ZIBs. The alloy network can not only stabilize

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Stable Aqueous Anode‐Free Zinc Batteries Enabled by

Anode-free zinc batteries (AFZBs) are proposed as promising energy storage systems due to their high energy density, inherent safety, low cost, and simplified fabrication process. However, rapid capacity fading caused by the side

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Realizing high-areal-capacity anode-free Zn metal batteries

A high-areal-capacity aqueous anode-free zinc battery (AFZMB) is realized by isosorbide dimethyl ether (IDE)-based co-solvent electrolyte. IDE not only lowers water reactivity and freezing point of the electrolyte, but also guides epitaxial Zn plating at high areal capacity. Consequently, Cu||ZnNVO full battery exhibits cutting-edge

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(PDF) Zinc battery goes to anode-free

An anode-free Zn-Br2 battery using the Sb/Sb2Zn3-heterostructured interface@Cu anode shows an attractive energy density of 274 Wh kg−1 with a practical pouch cell energy density of 62 Wh...

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Stable anode-free zinc-ion batteries enabled by alloy network

Newly-proposed anode-free zinc-ion batteries (ZIBs) are promising to remarkably enhance the energy density of ZIBs, but are restricted by the unfavorable zinc deposition

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An anode-free aqueous dual-ion battery

Aqueous dual-ion batteries are promising contenders for future applications due to their environmental friendliness, salient safety and cost-effectiveness. Herein, a novel anode-free aqueous dual-ion cell is proposed. Besides, electrolytes with inorganic/organic hybrid zinc salts are adopted to optimize its

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Toward a Metal Anode‐Free Zinc‐Air Battery for Next‐Generation Energy

Novel anode-free zinc-air batteries show potential to improve the rechargeability of this emerging sustainable energy storage technology. Electrodeposition from the electrolyte eliminates the need for conventional and typically oversized zinc anodes, while carbon nanotubes provide precise control of zinc deposition, resulting in

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Anode-free post-Li metal batteries

Anode-free metal batteries (AFMBs) are a new architecture of battery technology that relies solely on current collectors (CCs) at the anode side, eliminating the need for traditional metal anodes. This approach can pave the way for higher energy densities, lower manufacturing costs, and lower environmental f Recent Review Articles

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A breakthrough in inexpensive, clean, fast-charging batteries

A breakthrough in inexpensive, clean, fast-charging batteries First anode-free sodium solid-state battery Date: July 3, 2024 Source: University of Chicago

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Toward a Metal Anode‐Free Zinc‐Air Battery for

Novel anode-free zinc-air batteries show potential to improve the rechargeability of this emerging sustainable energy storage technology. Electrodeposition from the electrolyte eliminates the need for conventional and

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6 FAQs about [Anode-free zinc new energy battery]

Are anode-free zinc batteries a promising energy storage system?

Anode-free zinc batteries (AFZBs) are proposed as promising energy storage systems due to their high energy density, inherent safety, low cost, and simplified fabrication process. However, rapid capacity fading caused by the side reactions between the in situ formed zinc metal anode and electrolyte hinders their practical applications.

Are zinc-air batteries anode-free?

The anode-free concept in zinc-air batteries clearly shows that the deposition from the electrolyte can be preferable to the use of standard metallic zinc anodes.

Are Zn-based batteries anode-free?

However, the Zn-based batteries developed so far utilize an excess amount of Zn (i.e., thick Zn metal anode), which decreases the energy density of the whole battery. Herein, we demonstrate an anode-free design (i.e., zero-excess Zn), which is enabled by employing a nanocarbon nucleation layer.

Can aqueous anode-free zinc batteries form a stable interphase?

The work may initiate the research of AFZBs and be useful for the design of high energy, high safety, and low-cost power sources. The authors declare no conflict of interest. Aqueous anode-free zinc batteries (AFZBs) enabled by electrolyte engineering to form a stable interphase are constructed.

What is the charging capacity of an anode-free battery?

As the anode-free battery had no active material in the form of a zinc anode, the electrolytically deposited zinc was determined using Faraday's laws and standardized to the electrode mass. This resulted in a charging capacity of 819 mAh g −1, which corresponded to the theoretical capacity of zinc.

Are Zn-MNO 2 batteries anode-free?

Using this anode-free configuration, we showcase a Zn–MnO 2 battery prototype, showing 68.2% capacity retention after 80 cycles. Our anode-free design opens a new direction for implementing aqueous Zn-based batteries in energy storage systems. To access this article, please review the available access options below. Read this article for 48 hours.

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